Syllable division derived from spelling — this word is not in the pronouncing dictionary, so no phonetic transcription is shown rather than a guessed one.
perfidiously is an adverb meaning "in a perfidious manner". It carries one recorded sense.
in a perfidious manner
“he was playing perfidiously one side against the other”
Definitions, synonyms and semantic relations for perfidiously come from Princeton University’s WordNet. Commonness is measured against a corpus of everyday English. Full sources and licences.