Syllable division derived from spelling — this word is not in the pronouncing dictionary, so no phonetic transcription is shown rather than a guessed one.
five-membered is an adjective meaning "of a chemical compound having a ring with five members". It carries one recorded sense.
of a chemical compound having a ring with five members
Definitions, synonyms and semantic relations for five-membered come from Princeton University’s WordNet. Commonness is measured against a corpus of everyday English. Full sources and licences.