Syllable division derived from spelling — this word is not in the pronouncing dictionary, so no phonetic transcription is shown rather than a guessed one.
101st is an adjective meaning "the ordinal number of one hundred one in counting order". It carries one recorded sense.
the ordinal number of one hundred one in counting order
Definitions, synonyms and semantic relations for 101st come from Princeton University’s WordNet. Commonness is measured against a corpus of everyday English. Full sources and licences.