WordNet records no synonym and no antonym for tithe. It is the only member of each of its synsets, which is common for technical, taxonomic and single-sense vocabulary — there is no other English word that means the same thing. The broader and narrower terms below are the useful relations in that case.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
exact a tithe from
“The church was tithed”
levy a tithe on (produce or a crop)
“The wool was tithed”
pay a tenth of one's income, especially to the church
“Although she left the church officially, she still tithes”
1 of the 6 recorded senses carries no synonym, antonym or related term, so it is not shown above. Every sense, with its definition and examples, is on the full entry for tithe.
Synonyms, antonyms and the broader and narrower relations for tithe come from Princeton University’s WordNet. Full sources and licences.