WordNet records no synonym and no antonym for superannuate. It is the only member of each of its synsets, which is common for technical, taxonomic and single-sense vocabulary — there is no other English word that means the same thing. The broader and narrower terms below are the useful relations in that case.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
retire and pension (someone) because of age or physical inability
become obsolete
Synonyms, antonyms and the broader and narrower relations for superannuate come from Princeton University’s WordNet. Full sources and licences.
retire or become ineligible because of old age or infirmity