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structural has 4 distinct synonyms spread across 2 of its 6 senses. Each sense below keeps its own list, because a synonym belongs to a meaning and not to a word: swapping one sense's substitute into another sense's sentence is how a thesaurus makes writing worse. WordNet records no antonym for it — antonymy is a relation between word forms rather than concepts, so it is deliberately sparse.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
pertaining to geological structure
“geomorphological features of the Black Hills”
relating to or concerned with the morphology of plants and animals
“morphological differences”
4 of the 6 recorded senses carry no synonym, antonym or related term, so they are not shown above. Every sense, with its definition and examples, is on the full entry for structural.
Synonyms, antonyms and the broader and narrower relations for structural come from Princeton University’s WordNet. Full sources and licences.