pi has 8 distinct synonyms spread across 3 of its 5 senses. Each sense below keeps its own list, because a synonym belongs to a meaning and not to a word: swapping one sense's substitute into another sense's sentence is how a thesaurus makes writing worse. WordNet records no antonym for it — antonymy is a relation between word forms rather than concepts, so it is deliberately sparse.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
the ratio of the circumference to the diameter of a circle; approximately equal to 3.14159265358979323846...
someone who can be employed as a detective to collect information
the scientist in charge of an experiment or research project
the 16th letter of the Greek alphabet
an antiviral drug used against HIV; interrupts HIV replication by binding and blocking HIV protease; often used in combination with other drugs
Synonyms, antonyms and the broader and narrower relations for pi come from Princeton University’s WordNet. Full sources and licences.