orderly has 2 distinct synonyms spread across 2 of its 4 senses. Each sense below keeps its own list, because a synonym belongs to a meaning and not to a word: swapping one sense's substitute into another sense's sentence is how a thesaurus makes writing worse. Its one recorded opposite is disorderly.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
a male hospital attendant who has general duties that do not involve the medical treatment of patients
devoid of violence or disruption
“an orderly crowd confronted the president”
Synonyms, antonyms and the broader and narrower relations for orderly come from Princeton University’s WordNet. Full sources and licences.