WordNet records no synonym and no antonym for ligament. It is the only member of each of its synsets, which is common for technical, taxonomic and single-sense vocabulary — there is no other English word that means the same thing. The broader and narrower terms below are the useful relations in that case.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
a sheet or band of tough fibrous tissue connecting bones or cartilages or supporting muscles or organs
any connection or unifying bond
Synonyms, antonyms and the broader and narrower relations for ligament come from Princeton University’s WordNet. Full sources and licences.