WordNet records no synonym and no antonym for goody-goody. It is the only member of each of its synsets, which is common for technical, taxonomic and single-sense vocabulary — there is no other English word that means the same thing. The broader and narrower terms below are the useful relations in that case.
Counts are distinct word forms across every sense. A synonym that appears under three senses is counted once here and shown three times below, under each sense it belongs to.
a person who behaves extremely well in order to please a superior
1 of the 2 recorded senses carries no synonym, antonym or related term, so it is not shown above. Every sense, with its definition and examples, is on the full entry for goody-goody.
Synonyms, antonyms and the broader and narrower relations for goody-goody come from Princeton University’s WordNet. Full sources and licences.